There are a set of API calls that work with extended paths, and some do not. MSDN usually mentions this.
Not that just entering this path in windows explorerunder xp doesn't work, because the extended path syntax is just an escape sequence for the WIn32 API, not for Windows Explorer. Now, in Win7, this works because many people expected this to work.
Also for long paths this helps if you change the working directory or open the explorer with a subdirectory as root.
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