They do not represent the same thing.
"CET" always UTC + 01: 00
"Europe/Berlin" alternates between CET (UTC + 01: 00) in the winter, and CEST (UTC + 02: 00) in the summer.
See also:
As for editing, Europe/Rome is a separate time zone. This is not the same as Europe/Berlin , but Europe/Zurich , Europe/Amsterdam . At least not for their whole story.
If you compare their definitions (using the links in the previous paragraph), you will see that each of them complies with the EU rule for CET / CEST at some point in their past. Rome and Berlin since 1980, Zurich since 1981 and Amsterdam since 1977. Until these dates, they varied significantly. Other time zones also have different rules.
If you are interested in the history of these zones, I suggest reading the europe data in the TZ data. Comments are very interesting.
On the other hand, if you work only with modern dates, when all zones follow the same rules and offsets, then you can consider their substitutions - at least until they change in the future.
In addition, there are some time zones that are simply aliases and are completely interchangeable. In TZ data, they are called "links." For example, you can see here that Europe/Vatican and Europe/San_Marino are related to Europe/Rome and therefore equivalent.
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