It seems you just need to change the font in SQL Developer. Check out this SQLFiddle .
There are two things in the question text: get the Unicode character from it. nchr() should use a function instead of chr() . Secondly, the constant string '₹' , processed as varchar2 , and for the nvarchar2 constant to be specified correctly, you must add N to this literal: N'₹' .
To change the font, simply open the menu Tools -> Preferences ...

and select Code Editor -> Fonts node. On this page, you can select a font from the Font Name drop-down list. Copy and run the rupee symbol in the Sample Text field to see if the fonts are acceptable. Arial (on win7) works fine for me:

This parameter changes the font of the grid, as well as the font in the code editor:

In the above steps, you will only get half way to get full support for the rupee symbol, because select N'₹' from dual will only return a question mark. This is due to the conversion of the text encoding of the request between the client and server sides.
To solve this problem, Oracle provides an ORA_NCHAR_LITERAL_REPLACE environment setting . This parameter allows the client API to analyze the request text for character constants with the prefix N and use a special internal format for encoding such data on the client side before sending the request text to the server. Unfortunately, SQL Developer uses the Thin JDBC API, which ignores this environment setting, so adding this environment variable does not solve the problem.
But there is another way to enable the same behavior with the oracle.jdbc.convertNcharLiterals property, which acts at the system and connection level.
To enable this property, find the ide.conf file in the sqldeveloper\ide\bin in the SQL Developer installation folder and add this line to the end of the file:
AddVMOption -Doracle.jdbc.convertNcharLiterals=true
Save the file and restart SQL Developer, everything should work now:

PS In instructions based on SQL Developer version 3.2, older versions may have a different configuration file location. For instance. sqldeveloper\bin\sqldeveloper.conf .