First you need to create a break paragraph
Paragraph PageBreakParagraph = new Paragraph(new DocumentFormat.OpenXml.Wordprocessing.Run(new DocumentFormat.OpenXml.Wordprocessing.Break() { Type = BreakValues.Page }));
Then you need to add a paragraph
wordprocessingDocument.MainDocumentPart.Document.Body.Append(PageBreakParagraph)
You can also specify where to insert it if you do not want to add it to the end using the InsertAfter and InsertBefore methods
wordprocessingDocument.MainDocumentPart.Document.Body.InsertAfter(PageBreakParagraph, ReferenceElement); wordprocessingDocument.MainDocumentPart.Document.Body.InsertBefore(PageBreakParagraph, ReferenceElement);
Edit:
This adds a page break rather than a section break.
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