Instead of directly copying, you should use a symlink to avoid deleting previous SDKs for every Xcode update.
1.Open the terminal and navigate to the next SDK directory as shown below.
cd /Applications/Xcode.app/Contents/Developer/Platforms/iPhoneOS.platform/Developer/SDKs
2.Paste SDK 6.1 or your previously desired SDK in documents or in any other directory where it will not be deleted after future updates to Xcode. after you put the SDK in this directory, use the following command to create a symbolic link. (for simplicity, I put the SDK 6.1 in the Documents directory)
sudo ln -s /Users/.../Documents/iPhoneOS6.1.sdk .
NOTE. Remember to add a space and a period after the command.
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