The answer to the question is that this is not possible. Here is the answer from Microsoft MVP
So, do you want the client machine to proactively select one of the adpater network interfaces (installed on it) to send WCF requests? I am afraid that this is because of WCF control, since WCF focuses only on the following addresses:
** when they behave as a host, we can choose a binding to a specific host name / address to listen to client requests ** when they behave as a client, we can choose a destination address / host name to send a request.
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