Howard has already given the correct answer if the labels are Pi , 2 Pi , etc. are in the values ββof Pi , 2 Pi , etc.
Sometimes you may need to use placeholder tags with specific values ββwithout rescaling the data.
One of the other examples in the documentation shows how:
Plot[Sin[x], {x, 0, 10}, Ticks -> {{{Pi, 180 \[Degree]}, {2 Pi, 360 \[Degree]}, {3 Pi, 540 \[Degree]}}, {-1, 1}}]

I have a set of small custom functions for formatting Ticks as I want them. This is probably too much information if you are just starting out, but you should know that you can use any number format and, if you want, replace anything with your ticks.
myTickGrid[min_, max_, seg_, units_String, len_?NumericQ, opts : OptionsPattern[]] := With[{adj = OptionValue[UnitLabelShift], bls = OptionValue[BottomLabelShift]}, Table[{i, If[i == max, DisplayForm[AdjustmentBox[Style[units, LineSpacing -> {0, 12}], BoxBaselineShift -> If[StringCount[units, "\n"] > 0, adj + 2, adj]]], If[i == min, DisplayForm@AdjustmentBox [Switch[i, _Integer, NumberForm[i, DigitBlock -> 3, NumberSeparator -> "\[ThinSpace]"], _, N[i]], BoxBaselineShift -> bls], Switch[i, _Integer, NumberForm[i, DigitBlock -> 3, NumberSeparator -> "\[ThinSpace]"], _, N[i]]]], {len, 0}}, {i, If[Head[seg] === List, Union[{min, max}, seg], Range[min, max, seg]]}]]
And installation:
Options[myTickGrid] = {UnitLabelShift -> 1.3, BottomLabelShift -> 0} SetOptions[myTickGrid, UnitLabelShift -> 1.3, BottomLabelShift -> 0]
Example:
Plot[Erfc[x], {x, -2, 2}, Frame -> True, FrameTicks -> {myTickGrid[-2, 2, 1, "x", 0.02, UnitLabelShift -> 0], myTickGrid[0, 2, {0.25, .5, 1, 1.8}, "Erfc(x)", 0.02]}]
