Well, basically not, but you can do something using the user agent string and deny access (assuming Apache)
<Location /sitemap.xml> SetEnvIf User-Agent GodBot GoAway=1 Order allow,deny Allow from all Deny from env=!GoAway </Location>
But as they say here (where I found the syntax)
Attention:
Access control using the User-Agent is an unreliable technique, because the User-Agent Header can be installed in anything, at the whim of the end user.
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