eqs = {x1, 3 x1 - x2, x2 - x1};
Reduce[Max[eqs] >= 2 Min[eqs], {x1, x2}, Reals]
If you want to make comparisons with the second largest or third largest / smallest, then you can use RankedMax
x2 - x1 x2, , RegionPlot
RegionPlot[Max[eqs] >= 2 Min[eqs], {x1, 0, 1}, {x2, 0, 1}, PlotPoints -> 100]