Yes, it is possible, but first you need to transfer all the table spaces to backup mode and then display them (for example, ALTER TABLESPACE x BEGIN BACKUPand ALTER TABLESPACE x END BACKUP), you will need to check the syntax and make sure that it is suitable for your situation!). A huge simplification, this tells Oracle not to write to any of the data files, so they are all in a consistent state.
The two main problems that you encounter are that individual files are updated while they are being copied, so one file may be damaged; and more noticeably, different files have different internal timestamps and sequences, so Oracle will not allow them to be used.
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