Try to help msdeploy.exe.
msdeploy.exe -help -postSync
or
http://technet.microsoft.com/en-us/library/ee619740(WS.10).aspx
msdeploy -verb:sync -source:contentPath="C:\Test1"
-dest:contentPath="C:\Test2" -preSync:runcommand="Appcmd stop sites
MyWebSite" -postSync:runcommand="Appcmd start sites MyWebSite"
msdeploy -verb:sync -source:contentPath="C:\Test1"
-dest:contentPath="C:\Test2" -preSync:runcommand="c:\MyBatchFile.bat"
msdeploy -verb:sync -source:contentPath="C:\Test1"
-dest:contentPath="C:\Test2" -postSync:runcommand="c:\MyBatchFile.bat"
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