Another variant:
string s = Regex.Replace("1234567", @"^\w{3}", "$&/$&"););
This will capture 123and replace it with 123/123, leaving the tail 4567.
^\w{3} - Matches the first 3 characters.$& - replace all match.
You can also @"^(\w{3})", "$1/$1"if you prefer; it is better known.