It depends on which site you want to build, as well as on your knowledge and experience in creating websites.
If you know your material and are confident in your ability to work "close to metal" (as it were), I would imagine that you could build a faster website using ASP.NET MVC, since you could optimize your to have as little overhead as possible. However, you can build a very fast site using standard ASP.NET, so it really depends on the requirements of your project.
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