here you go, this should do the trick .... You need to set the width of the header template to the width of the expander.
<Expander Name="expOneDay"
HorizontalAlignment="Stretch"
HorizontalContentAlignment="Stretch" Width="Auto">
<Expander.Header >
<Border Background="Bisque">
<TextBlock Foreground="White" Text="Steve"
Width="{Binding ElementName=expOneDay, Path=ActualWidth}"
HorizontalAlignment="Stretch" />
</Border>
</Expander.Header>
</Expander>
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