Yes. Microsoft discusses SortedDictionary here .
The couple cites this page, which indicates that sorting is automatic:
"The SortedDictionary < (Of < (TKey, TValue > ) > ) O (log n) n - .
O (log n) lookup (), - , .
"SortedDictionary < (Of < (TKey, TValue > ) > ) : O (log n) O (n) SortedList < (Of < (TKey, TValue > ) > )."
, O (log n) , , .
.