<Line X1="0" Y1="0" X2="0" Y2="1" Stretch="Fill" Stroke="#FF000000" />
Works in both WPF and Silverlight.
If X is 0, this is a vertical line. If Y is 0, then it is horizontal. Use X1 = 0 Y1 = 0 X2 = 1 Y2 = 1 for diagonals from upper left to lower right or flip it in the lower left upper right corner.
Cheerful fresh.