Switching to the MVC Preview 4 code I have before me the overload for the Html.ActionLink () that you are using is:
public string ActionLink(string linkText, string actionName, object values);
Note that the second parameter is the name actionName, not the name of the route.
, :
Html.ActionLink("Items", "Items", new { UserID = 1 })
:
<a href="<%=Url.RouteUrl("UserItems", new { UserId = 1 })%>">Items</a>