On Linux systems, you can check the macro __BYTE_ORDERto see if it is __LITTLE_ENDIANor __BIG_ENDIAN. Although this is not authoritative, in practice it should work.
, , struct iphdr netinet/ip.h, IP-. 4- , , :
struct iphdr
{
#if __BYTE_ORDER == __LITTLE_ENDIAN
unsigned int ihl:4;
unsigned int version:4;
#elif __BYTE_ORDER == __BIG_ENDIAN
unsigned int version:4;
unsigned int ihl:4;
#else
# error "Please fix <bits/endian.h>"
#endif
u_int8_t tos;
u_int16_t tot_len;
u_int16_t id;
u_int16_t frag_off;
u_int8_t ttl;
u_int8_t protocol;
u_int16_t check;
u_int32_t saddr;
u_int32_t daddr;
};