When exporting a document with a package, you must compress it to a ZIP file. You can save a ZIP file with the same extension as your document format, but obviously this means that your application must handle both compressed and compressed versions of your file type. I asked a similar question to Apple Developer Technical Support, and they answered as follows:
Mail activity does not accept NSURLs indicating packages / packages. To split a package type document, you must compress it into a zip archive. Pass either the archive URL or the NSData object containing the archive data as an activity element.
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