The ruby system setup seems to be confusing. Try deleting the offensive /Library/Ruby/Site/2.0.0/rubygems.rb(and there may be more subfolders)
Ruby has its own rubigems /System/Library/Frameworks/Ruby.framework/Versions/2.0/usr/lib/ruby/2.0.0, so it should work with them.
, rubygems sudo gem update --system, , , rvm (rvm.io), brew.