You can set the color of the application title bar using the ApplicationViewTitleBar class :
var appView = Windows.UI.ViewManagement.ApplicationView.getForCurrentView();
appView.titleBar.backgroundColor = Windows.UI.Colors.black;
appView.titleBar.inactiveBackgroundColor = Windows.UI.Colors.black;
appView.titleBar.buttonBackgroundColor = Windows.UI.Colors.black;
appView.titleBar.buttonHoverBackgroundColor = Windows.UI.Colors.black;
appView.titleBar.buttonPressedBackgroundColor = Windows.UI.Colors.black;
appView.titleBar.buttonInactiveBackgroundColor = Windows.UI.Colors.black;
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