There is no way to instruct VS to build more than one configuration during assembly. From the point of view of VS, the build team creates a specific project or solution of projects using a single configuration (debugging and release are just two possible configurations).
However, you can use the post build command to do anything (including starting the build of a different configuration). However, just because you can do something post-build does not mean that it is best practice or even a good idea.
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