What you get is listwith one element of the dictionary inside. Get 0index dictionary :
>>> data = [{'expanded_url': 'http://twitter.com/voxdotcom/status/458708072131592194/photo/1', 'display_url': 'pic.twitter.com/uc3j0nU8uf', 'url': 'http://t.co/uc3j0nU8uf', 'media_url_https': 'https://pbs.twimg.com/media/Bl2oj5_CYAAO72v.png', 'id_str': '458708071875764224', 'sizes': {'small': {'h': 256, 'resize': 'fit', 'w': 340}, 'large': {'h': 773, 'resize': 'fit', 'w': 1023}, 'medium': {'h': 453, 'resize': 'fit', 'w': 599}, 'thumb': {'h': 150, 'resize': 'crop', 'w': 150}}, 'indices': [88, 110], 'type': 'photo', 'id': 458708071875764224, 'media_url': 'http://pbs.twimg.com/media/Bl2oj5_CYAAO72v.png'}]
>>> type(data)
<type 'list'>
>>> type(data[0])
<type 'dict'>
>>> data[0]['expanded_url']
'http://twitter.com/voxdotcom/status/458708072131592194/photo/1'
- pprint , :
>>> from pprint import pprint
>>> pprint(data)
[{'display_url': 'pic.twitter.com/uc3j0nU8uf',
'expanded_url': 'http://twitter.com/voxdotcom/status/458708072131592194/photo/1',
'id': 458708071875764224,
'id_str': '458708071875764224',
'indices': [88, 110],
'media_url': 'http://pbs.twimg.com/media/Bl2oj5_CYAAO72v.png',
'media_url_https': 'https://pbs.twimg.com/media/Bl2oj5_CYAAO72v.png',
'sizes': {'large': {'h': 773, 'resize': 'fit', 'w': 1023},
'medium': {'h': 453, 'resize': 'fit', 'w': 599},
'small': {'h': 256, 'resize': 'fit', 'w': 340},
'thumb': {'h': 150, 'resize': 'crop', 'w': 150}},
'type': 'photo',
'url': 'http://t.co/uc3j0nU8uf'}]