There is no event that fires when Node is clicked. However, here are some other events that may interest you:
AfterExpand - triggered immediately after the Node extension.
BeforeExpand - triggered before the Node extension.
FocusedNodeChanged - fires immediately after the Node focus changes (what happens when the user selects Node, regardless of whether they clicked on it or used the arrow to access).
I will also note that DevExpress has its own knowledge base with examples and sample code. It would be a great place to start your research for future questions: http://www.devexpress.com/Support/Center/
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