Adding an address to Envelope-To without adding it to To
You can use the MailMessage.Bcc property. Addresses added there will only be displayed in Envelope-To , and not in To mail:
message.Bcc.Add(" user@example.com ");
Adding an address to To without adding it to Envelope-To
Here I am absolutely sure that you are out of luck. I looked at the System.Net.Mail namespace using ILSpy and it seems like this is not possible. The To header of the mail is created from the To MailMessage property (see Message.PrepareHeaders), and the same property is used to fill the Envelope-To mail (along with Cc and Bcc , see SmtpClient.Send). Manually setting Headers["To"] will not help, since this value is overwritten by the contents of the To property (see Message.PrepareHeaders).
So, list@example.com will receive a copy of the message. Depending on the configuration of your SMTP server, this may result in a mail cycle.
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