Django can certainly be used to create a typographically clean and beautiful blog in HTML5 / CSS3, but it does not provide, for example, a basic blog template or CMS. If you are interested in creating a full blog (both appearance and basic features), then Django is a good choice.
You can create HTML pages yourself so that they look and behave as you wish. This is not like WordPress, which you can install and configure for the blog to work. However, there are many Django packages that you can add to your Django installation to easily create a blog.
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