I really hope you do not use the choice for this. The eselect compiler was killed many years ago because it was experimental and had many problems. gcc-config is what you should use. Unfortunately, it does not have support for each user, as we have for Java. You can always explicitly invoke a specific version (e.g. gcc-4.6.2 instead of gcc). If you create software using autotools, you can do it with ...
CC=gcc-4.6.2 ./configure make
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