For the Tomcat service, startup parameters are stored in the registry under the Options key at:
HKEY_LOCAL_MACHINE\SOFTWARE\Apache Software Foundation\Procrun 2.0\Tomcat<X>\Parameters\Java
(if necessary, replace the appropriate version of Tomcat).
Edit:
On a 64-bit version of Windows, the registry key:
HKEY_LOCAL_MACHINE\SOFTWARE\Wow6432Node\Apache Software Foundation\Procrun 2.0\Tomcat<X>\Parameters\Java
even if Tomcat runs on a 64-bit JVM.
source share