If you are trying to make them more similar, you can try to minimize the area of difference between the two polygons. That is, the area of the union of the two, minus the area of intersection between them.
The approximation would be to find two points with a maximum distance in each polygon (let's call them "diameters") and align them for two polygons.
For instance:
- The polygon A =
[(13, 12); (9, 14); (1,4); (5, 2)] [(13, 12); (9, 14); (1,4); (5, 2)] [(13, 12); (9, 14); (1,4); (5, 2)] (rhombus)- Diameter =
[(13, 12); (1,4)] [(13, 12); (1,4)] (length 14.4 )
- The polygon B =
[(14, 11); (8, 17); (3,24); (9, 18)] [(14, 11); (8, 17); (3,24); (9, 18)] [(14, 11); (8, 17); (3,24); (9, 18)] (another rhombus)- Diameter =
[(14, 11); (3,24)] [(14, 11); (3,24)] (length 17.0 )
Polygon B is shifted and rotated so that the diameters align:
[(14.08465297, 12.72310198); (7.439737081, 7.446257009); (-0.084652970, 3.276898021); (6.560262919, 8.553742991)]

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