The completely correct answer in the comments, of course, but if you only do one thing to prepare for Python 3, make him learn to use parentheses with "print".
Python 2.x:
print 'Hello, World!'
Python 3.x:
print('Hello, World!')
This is the most common mistake in my code when I try to write Python 3.
(And since both methods work with 2.x, you could also go and get used to using parens!)
Rini source share