colgroup table: first-child td: first-child
From w3schools :
Note. For :first-child for work in IE, <!DOCTYPE> must be declared.
Update:
As DisgruntledGoat correctly mentions, td elements are not descendants of colgroup elements. But the first colgroup obviously always includes the first column, so this
table tr td:first-child
which selects the first td in each row should do this.
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