First of all, if you are not a masochist, I think you would prefer a tutorial on programming assembly language with machine code. The assembly language uses human-readable instructions, a kind of low-level programming language. Machine code is machine readable - suitable for machines that are not very good for wetware; -)
All Intel chips use some x86 instruction set options. The above Wikipedia article provides examples of assembly and machine code, as well as resources for learning assembly language (see External links at the bottom of the article).
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