Are all MS Word documents serialized in XML format?
The short answer is no.
Long answer: on each issue MS changed the format of text documents. Thus, Word 6.0 - 95 uses the format, Word 97 - 2002 (aka XP) use a different one, another - 2003, and another 2007 - another one.
Of course, each version can save and open documents in older formats (although new features usually cannot be saved in such old formats).
Formats before 2003 (.doc) are incremental updates of the previous ones and are based on a binary format.
The format introduced in Office 2007 (.docx) is XML-based and was enforced as the ISO standard "ISO / IEC 29500: 2008 Office Open XML", although the word itself does not fully comply with this standard. Note that Word 2007 can save (and open) documents in older binary formats.
Hope this helps.
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