Have you tried adding extension=php_curl.dll to php.ini?
FWIW, the best way to check phpinfo for the CLI is probably:
$ php -i | fgrep -i curl Configure Command => '/SourceCache/apache_mod_php/apache_mod_php-44.4/php/configure' '--prefix=/usr' '--mandir=/usr/share/man' '--infodir=/usr/share/info' '--disable-dependency-tracking' '--with-apxs2=/usr/sbin/apxs' '--with-ldap=/usr' '--with-kerberos=/usr' '--enable-cli' '--with-zlib-dir=/usr' '--enable-trans-sid' '--with-xml' '--enable-exif' '--enable-ftp' '--enable-mbstring' '--enable-mbregex' '--enable-dbx' '--enable-sockets' '--with-iodbc=/usr' '--with-curl=/usr' '--with-config-file-path=/etc' '--sysconfdir=/private/etc' '--with-mysql-sock=/var/mysql' '--with-mysqli=/usr/bin/mysql_config' '--with-mysql=/usr' '--with-openssl' '--with-xmlrpc' '--with-xsl=/usr' '--without-pear' curl cURL support => enabled cURL Information => libcurl/7.16.3 OpenSSL/0.9.7l zlib/1.2.3 $
php -i is basically the CLI equivalent of phpinfo()
Also, double check that the PHP CLI is configured to use the same php.ini (or if it uses a different file, make sure you edit it too). Sometimes PHP can be configured using another php.inis depending on how PHP is called - I believe that debian and Ubuntu do this in particular.
Determining the php.ini file to use:
$ php -i | fgrep Configuration Configuration File (php.ini) Path => /etc Loaded Configuration File => /etc/php.ini $
or
$ php --ini Configuration File (php.ini) Path: /etc Loaded Configuration File: /etc/php.ini Scan for additional .ini files in: /etc/php.d Additional .ini files parsed: /etc/php.d/apc.ini, /etc/php.d/dbase.ini, /etc/php.d/dom.ini, /etc/php.d/gd.ini, /etc/php.d/imagick.ini, /etc/php.d/json.ini, /etc/php.d/mbstring.ini, /etc/php.d/memcache.ini, /etc/php.d/mysql.ini, /etc/php.d/mysqli.ini, /etc/php.d/pdo.ini, /etc/php.d/pdo_mysql.ini, /etc/php.d/pdo_pgsql.ini, /etc/php.d/pdo_sqlite.ini, /etc/php.d/pgsql.ini, /etc/php.d/tidy.ini, /etc/php.d/xdebug.ini, /etc/php.d/xmlreader.ini, /etc/php.d/xmlwriter.ini, /etc/php.d/xsl.ini, /etc/php.d/zip.ini