If you want to just save the FlowDocument objects to the database without any processing, I would recommend using binary serialization and storing the resulting byte array in varbinary (max). It scales quickly and well.
However, if you already have XML FlowDocuments files, it would be easier to drop them into the nvarchar (max) field without additional (added) serialization / deserialization. This scales trivially for values โโbelow 8k, and then looks OK until you click the 10 MB mark.
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