All that Expression Blend can do, you can do in Visual Studio, but you will have to code some additional effects directly in XAML manually. Essentially, Expression Blend gives you automatic XAML generation for more attractive graphics that Visual Studio does not.
You will also find that it will guide you through the MVVM WPF / Silverlight pattern.
I could not recommend any particular resource on my own, but if you are looking for the MVVM WPF template on the Internet, there are many examples. Admittedly, many of them are Silverlight, but the basics are still there.
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