MAC addresses are specific to NICs. Each network interface will have its own MAC address. Thus, a modern computer with Wired Network (LAN Interface) support, as well as other types of network connections such as Wireless Network (WiFi), will obviously have several MAC addresses, one for each network interface.
If your computer connects to the router via WiFi, check the MAC address of your WiFi card. If on Windows just run ipconfig /all on the command line (command line), you can see the MAC address (physical address) for each network interface.
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